不同茶园武夷岩茶水仙关键呈香物质分析

Analysis of key aroma substances in Wuyi Rock Tea Shuixian of different tea gardens

  • 摘要: 【目的】 分析不同茶园武夷岩茶水仙的关键呈香物质,揭示不同产区武夷岩茶香气的差异性,为武夷岩茶的品质提升提供参考依据。【方法】 采用顶空固相微萃取(HS-SPME)结合气相色谱—质谱(GC-MS)对正岩区(百花岩、水帘洞)、半岩区(梅子桥、燕子窠)、洲茶区(上梅、黄土)3个茶区6个茶园水仙的挥发性化合物进行分离、鉴定,通过正交偏最小二乘判别分析(OPLS-DA)筛选关键呈香物质,结合香气活力值(OAV)分析不同产区茶园水仙香气的差异性。【结果】 6个茶园水仙样品中共检测到101种挥发性化合物,包括醇类12种、醛类14种、酸类5种、酮类12种、烷烃类3种、烯烃类9种、杂环化合物10种、酯类26种、其他类10种;6个茶园水仙样品共有挥发性化合物56种;醇类是水仙香气的主要成分。结合OAV分析,筛选出15种关键呈香物质,分别为β-紫罗兰酮、2,4-癸二烯醛、香豆素、癸醛、香叶基丙酮、α-紫罗兰酮、反式-橙花叔醇、β-环柠檬醛、橙花醇、苯乙醇、藏红花醛、茉莉酮、茉莉酸甲酯、苯乙醛、反式异丁香酚。百花岩和水帘洞茶园水仙的关键呈香物质分别有11和12种,均以花果香为主,甜香、青香、木香为辅;梅子桥、燕子窠、上梅和黄土茶园水仙的关键呈香物质分别有15、15、15和14种,以花香为主,蜡脂气、药草香、果香为辅。【结论】 OPLS-DA结合OAV分析,对6个茶园筛选出15种关键呈香物质;不同茶区香气特征有差异,正岩区以花果香为主,半岩区和洲茶区以花香为主。

     

    Abstract: 【Objective】 This study aimed to analyze the key aroma substances of the Wuyi Rock Tea Shuixian of diffe-rent tea gardens, reveal the aroma differences of Wuyi Rock Tea of various production areas, so as to provide a reference basis for the quality improvement of Wuyi Rock Tea.【Method】 Volatile compounds of Shuixian Tea of six tea gardens in three production areas (Zhengyan District: Baihuayan and Shuilian, Banyan District: Meiziqiao and Yanzike, Zhoucha District: Shangmei and Huangtu) were isolated and identified by headspace solid-phase microextraction (HS-SPME) with gas chromatography-mass spectrometry (GC-MS). Key aroma substances were screened via orthogonal partial least squares-discriminant analysis (OPLS-DA), and the aroma differences of Shuixian Tea of tea gardens of different production areas were analyzed according to odor activity value (OAV).【Result】 A total of 101 volatile compounds were detected in the Shuixian Tea samples from 6 tea gardens, including 12 alcohols, 14 aldehydes, 5 acids, 12 ketones, 3 alkanes, 9 alkenes, 10 heterocyclic compounds, 26 esters, and 10 other compounds; 56 common volatile compounds were shared by the Shuixian Tea samples from the 6 tea gardens; alcohols were the were the main components for the aroma. Based on OAV analysis, 15 key aroma substances were screened: β-ionone, 2,4-decadienal, coumarin, decanal, geranylacetone, α-ionone, trans-nerolidol, β-cyclocitral, nerol, phenethyl alcohol, safranal, jasmonone, methyl jasmonate, phenylacetaldehyde, and trans-isoeugenol. 11 and 12 key aroma compounds identified in the teas from Baihuayan and Shuiliandong, respectively, mainly demonstrated flowery and fruity notes, secondarily demonstrated sweet, green, and woody notes;15, 15, 15, and 14 key aroma compounds were found in Meiziqiao, Yanzike, Shangmei, and Huangtu numbered , respectively, mainly demonstrated flowery notes, secondarily demonstrated waxy, herbaceous, and fruity notes.【Conclusion】 According to OPLS-DA with OAV, 15 key aroma compounds are screened from 6 tea gardens; aroma characteristics also differ among production areas: Zhengyan District mainly shows floral-fruity notes, and Banyan District and Zhoucha District mainly show flowery notes.

     

/

返回文章
返回