吸附降解苯系物的不同生物源腐殖质材料比较分析

Comparison of different biogenic humus materials with adsorption and degradation of benzene series

  • 摘要: 【目的】使用农林废弃物作为主要生物源进行腐殖质堆肥发酵,分析不同腐殖质的组分及吸附苯系物的效果,旨在寻找适用于西北地区煤化工场地苯系物污染修复的高效腐殖质类材料,为采用生物法治理苯系物污染提供参考。【方法】选择苹果木枝条和猪粪为主要生物源,设纯果木枝条、纯猪粪、果木枝条与猪粪混合3个处理组,采用好氧堆肥方式(碳氮比25∶1)进行90 d发酵;对获得的腐殖质进行水溶性物质、腐殖酸、胡敏素及胡敏酸的有机碳(CWSS、CHE、CHu、CHA)含量检测,通过计算获得富里酸的有机碳(CFA)含量,并通过苯系物吸附效果筛选评估不同生物源材料的适用性。【结果】堆肥期间各处理组内的腐殖质组分消耗及生成情况不同。堆肥开始时(0 d),CWSS、CHE和CHA含量最高为纯猪粪组,分别为28.1、54.0和32.0 g/kg,最低为纯果木枝条组,分别为15.5、48.0和24.0 g/kg;CHu含量最高为纯果木枝条组(369.5 g/kg),最低为果木枝条与猪粪混合组(169.0 g/kg),二者间差异显著(P<0.05,下同);CHA/CFA最高为果木枝条与猪粪混合组(2.67),最低为纯果木枝条组(1.00),二者间差异显著。堆肥结束时(90 d),部分指标的处理组排序有变,CWSS含量最高为果木枝条与猪粪混合组(12.6 g/kg),最低为纯猪粪组(9.1 g/kg),二者间差异显著;CHA含量最高和最低分别为纯果木枝条组(22.1 g/kg)和果木枝条与猪粪混合组(15.0 g/kg),二者间差异显著;CHA/CFA最高和最低分别为纯果木枝条组(1.56)和果木枝条与猪粪混合组(0.83),二者间差异显著;苯系物吸附效果筛选发现纯果木枝条制备的腐殖质对苯系物的吸附效果最佳,吸附量达320 mg/kg。【结论】果木枝条堆肥制备的腐殖质对苯系物表现出优越的吸附性能,可作为修复西北地区煤化工场地苯系物污染的潜在高效材料。

     

    Abstract: 【Abstract】Agricultural and forestry wastes were used as the main biomass source for humus compost fermentation,and the composition of different humus and their adsorption effects on benzene series were analyzed to find efficient humus materials suitable for remediating benzene series pollution at coal chemical industry sites in northwestern China,and provide reference for treating pollution of benzene series by biological methods.【Method】Apple wood branches and pig manure were selected as the main biomass sources. Three treatment groups were set up:pure apple wood branches,pure pig manure,and a mixture of apple wood branches and pig manure. Aerobic composting,with a carbonto-nitrogen ratio of 25∶1,was used for a fermentation period of 90 d. The organic carbon contents of water-soluble substances,humic acid,humin and fulvic acid(referred to as CWSS,CHE,CHu,and CHA respectively)were determined in the obtained humus. The organic carbon content of fulvic acid(CFA)was calculated,and the applicability of different biomass source materials was assessed through screening their adsorption effects on benzene series.【Result】During the composting period,the consumption and formation of humic substances varied among different treatment groups. At the beginning of composting(0 d),the highest contents of CWSS,CHE,and CHA were observed in the pure pig manure group,measuring 28.1,54.0,and 32.0 g/kg respectively,while the lowest were found in the pure fruit tree branch group,with values of 15.5,48.0,and 24.0 g/kg respectively. The highest CHu content was observed in the pure fruit tree branch group(369.5 g/kg),while the lowest was found in the mixed group of fruit tree branches and pig manure(169.0 g/kg). The difference between the 2 groups was significant(P<0.05,the same below). The highest CHA/CFA ratio was observed in the mixed group of fruit tree branches and pig manure(2.67),while the lowest ratio was found in the pure fruit tree branch group (1.00),indicating a significant difference between the two. At the end of the composting process(90 d),the ranking of some indicators in the treatment groups changed. The highest CWSS content was observed in the mixed group of fruit tree branches and pig manure(12.6 g/kg),while the lowest was found in the pure pig manure group(9.1 g/kg),indicating a significant difference between the two. The highest and lowest contents of CHA were found in the pure fruit tree branch group(22.1 g/kg)and the mixed group of fruit tree branches and pig manure(15.0 g/kg)respectively,showing a significant difference between the two. The highest and lowest CHA/CFA ratios were observed in the pure fruit tree branch group (1.56)and the mixed group of fruit tree branches and pig manure(0.83)respectively,indicating a significant difference between the two. The screening,based on the adsorption effect of benzene series,revealed that humus prepared from pure fruit tree branches exhibited the best adsorption performance for benzene series,with an adsorption capacity of 320 mg/kg. 【Conclusion】The humus prepared from composting fruit tree branches exhibits superior adsorption properties for benzene series and has the potential to serve as an effective material for remediating benzene series contaminated sites in the coal chemical industry in the northwestern region.

     

/

返回文章
返回