壳聚糖基褐藻多酚可食膜的制备工艺优化

Preparation technology optimization of chitosan based phlorotannins edible films

  • 摘要: 目的优化壳聚糖基褐藻多酚可食膜的制备工艺,为可食性包装膜的开发和应用提供参考依据.方法以壳聚糖和羧甲基纤维素钠(CMC)为成膜基础材料,采用流延法制备可食膜,以抗拉强度、断裂伸长率和水蒸气透过率为考察指标,通过多指标综合评分结合正交试验的方法确定壳聚糖基褐藻多酚可食膜的最佳制备工艺,并对可食膜进行性能表征.结果各因素对壳聚糖基褐藻多酚可食膜物理性能的影响排序为壳聚糖浓度>甘油浓度>CMC浓度>褐藻多酚浓度,其中壳聚糖浓度和甘油浓度对可食膜的物理性能影响显著(P<0.05).优化后的可食膜制备工艺条件为:壳聚糖浓度1.5%、甘油浓度1.0%、褐藻多酚浓度0.4%、CMC浓度2.0%,在此条件下制得的可食膜物理性能较好,其平均拉伸强度为24.78 MPa,断裂伸长率为36.94%,水蒸气透过率为0.445 g·mm/(m2·h·kPa),综合评分69.06分.复合膜各组分间相容性较好,膜表面平整致密.结论优化工艺制得的壳聚糖基褐藻多酚可食膜具有良好的成膜性能和微观结构,为研发新型可食性包装膜提供了新思路.

     

    Abstract: ObjectiveThe preparation technology of chitosan based phlorotannins edible films was optimized,in or-der to provide theoretical references for the development and application of edible films.MethodUsing sodium carboxy-methyl cellulose(CMC)and chitosan as film materials,the edible films were prepared by tape casting method. With ten-sile strength,elongation at break and water vapor permeability as evaluation indexes,the optimal preparation conditions of edible films of chitosan based phlorotannins were determined by multi-index comprehensive scoring combined with or-thogonal test,and the properties of the edible films were characterized.ResultThe effects of each factor on physical properties of the edible films was ranked as follows:chitosan concentration>glycerol concentration>CMC concentration>polyacylphenol concentration,in which the chitosan concentration and glycerol concentration had significant effects on the physical properties of edible films(P<0.05). The optimal preparation conditions of edible films were obtained as fo-llows:chitosan concentration 1.5%,glycerol concentration 1.0%,phlorotannins concentration 0.4%and CMC concentra-tion 2.0%. Under the above optimum conditions,the edible films showed better physical properties with average tensile strength of 24.78 MPa,elongation at break of 36.94%,water vapor permeability of 0.445 g·mm/(m2·h·kPa)and com-prehensive score of 69.06. There were good compatibilities between components of the prepared composite edible films. The film surface was smooth and dense.ConclusionThe chitosan based phlorotannins edible films prepared by opti-mized technology have film-forming property and microstructure,which provides a new path for developing edible films.

     

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